Pessoal, tudo tranquilo?
Desculpem a demora em blogar de novo, mas é que eu estava na feira da ABTCP (Associação Brasileira de Tecnologia em Celulose e Papel). Por isso, minha semana foi muito corrida.
Felizmente, a correria da semana rendeu frutos: meu artigo foi um dos mais bem avaliados pela comissão julgadora. Dessa forma, vou publicá-lo aqui, para dividir com vocês. Saudações e aproveitem.
Multivariable Process Control Applications for the Pulp Industry
Authors:
Rafael Lopes, Rick Van Fleet, Daniel Figueiredo
1. INTRODUCTION
1.1 Overview
The production of cellulose pulp is a highly intensive process involving the interactions of numerous processes. The ability to make this process economically viable relies on good process design together with an understanding of the process dynamics. The present economic climate requires that cellulose producers are able to make good quality cellulose at the right price and in a timely manner. Best in class pulp and paper producers are aware of this and embrace every opportunity to gain an advantage. Multivariable control and site-wide optimization ultimately are an excellent choice to enable this.
1.2 MPC (Multivariable Predictive Control)
One of the effective and leading optimization and advanced control technologies is Multi-Variable Predictive Control (MPC). The philosophy of MPC is to predict the plant behavior, based on heuristic models, in order to take more timely preventive and corrective actions to ensure better regulation and plant stability. These models consider the interactions between the key plant variables.. In addition, the predictive capability of model-based MPC further reduces plant variability and allows operating closer to the real plant limits, enabling more productivity and cost reductions than any other advanced control technology.
While MPC is different than PID and Expert Systems, a common perception is that it is more difficult to apply. Actually, the reverse is true. The complexity of application is internal to the software, thus the implementer needs only to define models and then configure desired operation targets. Model definition has been made much easier through use of automated modelling software, process stepper applications, and on-line and on-control modelling software. In early methods such as Expert Rules, Fuzzy Logic, and complex PID strategies, the implementer needed to be a process and control expert, and careful attention to designing the system was very important. It becomes very important that the expert considers how to delivery the majority of benefits given the limitations of these control technologies. For example, expert system and complex PID strategies have difficulties in the following areas:
- Time-based dynamics require considerable skill and effort to implement, and thus are often eliminated or simplified to reduce cost and effort.
- Interactions from controls and processes require some skill and effort to implements, and thus are often eliminated or simplified to reduce cost and effort.
- Design, building, testing, commissioning, and maintaining a complex customized application, and the resulting complexity (cost) vs benefits achieved often is a challenge. Sustainability is general has also been an issue.
- Poor operator acceptance and utilization due to elimination and simplification of dynamics and interactions. Simply stated, the advanced controls do not properly respond to many situations. It is not uncommon to have less than 50% control utilization
MPC is widely accepted in the petrochemical industries, where traditionally there are high amount of base level automation and the potential benefits are large. Other industries outside of Petrochemical have been slow to adopt MPC, but that trend has been changing. The reliability and amount of automation in industries such as pulp and paper, chemical manufacturing and mining and metals have improved. In addition, in some markets original equipment manufacturers and local automation consultants have introduced and gained some acceptance of simple expert systems that are low-cost to implement for the supplier, but offer lower benefits for the customer. Today, MPC has been utilized in all these markets, but the widespread use and full acceptance is more a cultural issue rather than a technical issue.
In the MPC philosophy, the variables that have to be maintained inside a range or in a target value are called Controlled Variables (CVs). In order to achieve the operational objectives for the CVs, the application adjusts the variables called Manipulated Variables (MVs). These are sometimes referred to as the “handles”. In a “single output-single input”, SISO control, there is only one CV (the process value or controller input) and one MV (process output – valve opening). With MPC technology, there multiple MVs and CVs, as well as Disturbance Variables (DVs), which are measured disturbances that influence in the process. This type of controller is called a multiple input, multiple output or MIMO controller.
1.3 Robust Multivariable Predictive Control Technology
RMPCT technology represents an advance of the traditional MPC technologies. Like the others, this technology models the process, make the necessary predictions and uses multivariable control movements in order to: optimize the process, maintain the variables inside operational limits and respect the process and plant constraints. The performance gain and robustness is due to a patented feature called “range control algorithm” (RCA), which makes that the disturbances and prediction errors inherent to the process, considered in the future movement plan. The picture sketches how the RCA technology works.

Figure 1 – RCA Technique Controlling a CV Inside Limits
RCA minimizes the effects of the model uncertainties while determining the smallest process moves required to simultaneously meet control and optimization objectives. The correction horizon concept is that CV errors are reduced to zero at the correction horizon in the future. Prior to the correction horizon, the controller is free to determine any trajectory for the CV as long as the CV is brought within limits or to setpoint at the correction horizon. Because no trajectory is imposed on the controller, the controller has the freedom to determine a trajectory that requires minimum MV movement and is least sensitive to model error.
However, the correction horizon by itself does not say anything about what happens to the CV prior to the horizon. It is important that the controller does not transiently move a CV farther outside a limit while correcting other CV errors, even though all CVs are brought to zero error by their correction horizons. Limit funnels are used to prevent the controller from introducing transient errors prior to the correction horizons, by defining constraints on the CVs that are imposed at intervals from the current interval out to the horizon.
2. APPLYING ROBUST MULTIVARIABLE CONTROL TO PULP
The challenge to any pulp process is to minimise the cost of production per tonne of cellulose, consistent with quality, safety and environmental considerations. This translates to maximising the production of cellulose (plant flow and yield), rationalizing the chemical usage and perhaps minimising the energy costs per tonne of product.
There are a number of areas within a typical cellulose pulp plant that are well suited to the application of advanced process control. Significant benefits can be derived from these by continuously pushing the various process limits. The benefits can be described bellow:
Table 1 – Typical MPC Benefits for Pulp
|
MPC Solution
|
Typical $/Ton Savings
|
*Typical $/yr (Savings & Prod Increase)
|
Other Typical Benefits
|
|
Digester – Continuous
|
$ 1.00 – 2.00
|
$ 600k – $1.5M
|
Production increase 1-3%, Pulp Quality, Bleaching Cost
|
|
Digester – Batch
|
$ 2.00 – 4.00
|
$ 700k – $3M
|
Production increase 2-8% , Pulp Quality, Bleaching
|
|
O2 Delignification
|
$ 0.50 – 2.50
|
$150k – $300k
|
Environmental, Bleaching Cost, Helps de-bottleneck the evaporators
|
|
Brownstock Washing
|
$ 0.50 – 2.50
|
$300k – $600k
|
Environmental, Bleaching Cost, Pulp Quality
|
|
CLO2 Generation
|
$ 0.30 – 2.00
|
$ 200K – $600K
|
Product Quality, Productivity
|
|
Bleach Plant
|
$ 1.50 – 3.50
|
$ 350k – $750k
|
Bleach Cost, Pulp brightness, Productivity
|
|
Causticizing
|
$ 0.40 – 2.00
|
$150k – $300k
|
Stable %CE and white liquor strength, Productivity, Reduce dead-load
|
|
Lime Kiln
|
$ 0.50 – 1.50
|
$200k – $500k
|
Energy Savings, Lime Quality (e.g. residual carbonate), Productivity, Environmental
|
|
Evaporator
|
$ 0.25 – 1.00
|
$250k – $1M
|
Energy Savings, Productivity, BL Solids Stable to Recovery Boiler
|
|
Recovery Boiler
|
$ 2.50 – $4.0
|
$400k – $1.5M
|
This solution is made up of 8 different modules with benefits associated with each. This ranges from increased steam production, increased liquor burning, reduced soot-blowing steam, reduced plugging, etc…
|
|
TMP
|
$ 2.00 – 5.00
|
$300k – $2M
|
Energy Savings, Purchased Kraft savings, Pulp Quality
|
|
De-Inking
|
$ 0.20 – 2.00
|
$100k – $350k
|
Pulp variability reduction in brightness, Productivity
|
* These values are dependant on plant size and configuration but are typical.
2.1 ROBUST MULTIVARIABLE CONTROL Solution for Continuous Cooking
The main objective of this area is to safely produce pulp of the desired quantity and quality, with the minimum consumption of chips, chemicals and energy. The typical main variable interactions in this area are described in the following table.
Table 2 – Main Variables in the Continuous Digestion for Pulp and Paper
|
Controlled Variable
|
Manipulated Variable
|
|
Chip Bin Level
|
Wood Flow
|
|
Production Rate
|
Chip Meter / Blow Flow
|
|
Alkali-to-Wood
|
White Liquor Flow
|
|
Liquid-to-Wood
|
Black Liquor Flow
|
|
IV Chip Level (Dual Vessel)
|
Chip Meter / IV Sluice Flow
|
|
Digester. Chip Level
|
Chip Meter / Blow Flow
|
|
Digester. Liquor Level (Vap. Phase)
|
Extraction Flow
|
|
Residual Alkali
|
Alkali-to-Wood
|
|
Dilution Factor
|
Extraction Flow / Cold Blow
|
|
Blow Consistency
|
Counter Wash Flow
|
|
Kappa Number
|
UH Temp / LH Temp
|
|
Coordinated Rate Change
|
All
|
|
Coordinated Grade Change
|
All
|
In order to implement the MPC in this area, these interactions are considered in the control matrix. It is necessary to excite the process, often referred to as step tests or bump test, to gain information about the relationships. Through step tests, it is possible to model the interactions, which are also important to be considered.
In this case, the proven benefits achieved were:
- 30 – 40% Reduction in K/KAPPA Variation
- 0.5 – 2% Increase in Yield
- 2 – 5% Increase in Throughput
- 3 – 6% Reduction in Cooking Chemical Usage
- Reduction in Bleaching Chemical Usage
- Improved Process Visibility
2.2 MPC for Brownstock Washing
The main objectives of this area in a pulp mill are:
- Produce clean pulp for bleaching or papermaking by separating black liquor from blown digester pulp
- Accomplish with an acceptable economic balance of:
- Minimal carryover of spent cooking liquor and dissolved lignin in pulp (minimal “soda loss”)
- Maximum solids in weak liquor (H2O must be evaporated- $$)
- Minimal discharge to sewer (environmental permit issue)
- Minimal use of hot process wash water (energy-$$)
For this case, the main interactions in this area are:
Table 3 – Main Variables in the Brown Stock Washing for Pulp and Paper
|
Controlled Variable
|
Manipulated Variable
|
|
Filtrate Tanks Level 1st stage
|
Shower Flow 1st stage
|
|
Filtrate Tank Level 2nd stage
|
Shower Flow 2nd stage
|
|
Filtrate Tank Level 3rd stage
|
Shower Flow 3rd stage
|
|
COD (PV)
|
Dilution Factor (SP)
|
|
% Solids (PV)
|
Dilution Factor (SP)
|
In this case, the proven benefits achieved were:
- Optimized washing to clean pulp and reduce soda losses
- Minimized defoamer usage
- Optimized refining to improve fiber properties and reduce energy
- Maintained screening effectiveness throughout operating range by adjustment of reject and dilution flows
- Maintained production through automatic wiping of screens, knotters, or fibrilizers
2.3 MPC for Bleaching
Bleaching is a chemical process applied to pulp fibers in order to increase their brightness. It has to be accomplished, subject to the following operational constraints:
- Without compromise strength properties of the bleached pulp
- With minimum cost
- Without expose personnel to toxic chemicals
- With minimum impact on the environment
The main bleaching chemicals used are:
Table 4 – Bleaching Chemicals
|
Oxidant
|
Function
|
Advantages
|
Disadvantages
|
|
Chlorine (C )
|
Oxidize and chlorinate lignin
|
Effective, economical delignification; good particle removal
|
Organochlorine formation (environmental concern)
|
|
Hypochlorite
(H)
|
Oxidize, decolorize, and solubilize lignin
|
Easy to make and use; low cost
|
Can cause loss of pulp strength; chloroform formation
|
|
Chlorine dioxide (ClO2) (D)
|
1) Oxidize, decolorize, and solubilize lignin
2) In small amounts with chlorine, protects against cellulose degradation.
|
Achieves high brightness without loss of pulp strength; good particle bleaching.
(Better than chlorine for environment)
|
Must be made on-site; cost; some organochlorine formation; highly corrosive
|
Oxygen (O2) (O)
|
Oxidize and solubilize lignin
|
Low chemical cost; provides chloride-free effluent for recovery (good for environment)
|
Requires significant capital equipment when used in large amounts; potential loss of pulp strength
|
|
Hydrogen peroxide (H2O2) (P”)
|
Oxidize and decolorize lignin
|
Easy to use; low capital cost (good for environment)
|
High chemical cost; poor particle bleaching; can cause loss of pulp strength
|
Ozone (O3) (“Z”)
|
Oxidize, decolorize, and solubilize lignin
|
Effective; provides chloride-free effluent for recovery (good for environment)
|
Must be made on-site; cost; poor particle bleaching and pulp strength
|
Alkali “Extraction” (NaOH)
|
Hydrolyze chlorolignin and solubilize lignin
|
Effective and economical
|
Darkens pulp
|
Chelants (added to P) EDTA or DTPA
|
Remove metal ions
|
Improves peroxide selectivity and efficiency
|
Cost
|
For this application, some of the control matrix variables could be
Table 5 – Main Variables in the Bleaching for Pulp and Paper
|
Controlled Variable
|
Manipulated Variable
|
|
Residual Chemicals
|
Chloride Dioxide Addition
|
|
pH’s
|
Caustic Soda Addition
|
|
Final Brightness
|
Sulphuric Acid Addition
|
|
Tower Temperatures
|
Oxygen Addition
|
|
Tower Pressure Differentials
|
Peroxide Addition
|
|
|
Steam Additions
|
In this case, the proven benefits achieved were:
- Reduction of chemical usage: 2 – 4%
- Energy savings, due to a better tower temperature control
- Increase in plant stability à Directly translated on Production Increase (around 1 to 5%, depending on how big is the plant variability)
2.4 MPC for Evaporation
The main objectives for this area are:
- Remove water from black liquor to match input / recovery demand with minimum steam
- Maximize % Total Dissolved Solids (TDS) to Recovery Boiler
- Minimize fouling effects / Operate at maximum uptime
- Control evaporators levels
The evaporator plant consists in multiple heat exchangers (effects) in series. It removes water from Weak Black Liquor (WBL), which comes from brownstock washers, digesters and/or O2 delignification to WBL storage(s). Typically, there are around 14-18% Total Dissolved Solids (TDS) in the stream and at the end of the operation, the strong black liquor has 68-72% of TDS.
The main interactions in this area to be considered in the RMPCT are:
Table 6 – Main Variables in the Evaporation for Pulp and Paper
|
Controlled Variable
|
Manipulated Variable
|
|
Production Rate Control
|
Feed liquor control, Intermediate liquor control, Semi-strong liquor control, Steam control
|
|
Strong Black Liquor Dry solids control
|
Steam control
|
|
Feed liquor control
|
Intermediate liquor control
|
|
Evaporation Stages Levels
|
|
|
Evaporation Stages Pressures
|
|
The main proven benefits for the evaporation system are:
- Production increase
- Increased liquor flows by operating closer to constraints, including: Levels, Condensate quality, Pump Loads
- Minimise Bypass flows
- Typical Number: 0.25 to 0.5% decrease in soda losses
- Increased yield
- improvements in the amount of evaporation allows more production
- improvements in the control of the liquor (digestion) temperature: maximize recirculation flows and limit liquor temperate
- Typical Number: 0.25 to 0.5% throughput increase (digestion yield)
- 0.25oC to 0.5oC temperature for evaporation decrease, due to reduced variability. This diminution on the temperature is straightly translated on steam saving.
2.6 MPC for Slaker/Causticizing
The main objective of this area is to convert green liquor from recovery to white liquor for the digester operation. The main reactions are:
CaO + water ====> Ca(OH)2 + HEAT (slaking)
Ca(OH)2 + Na2CO3 ====> 2 NaOH + CaCO3 (causticizing)
The main problems found on this area are:
- Not efficient clarification à Generally caused by the lime feed quality
- Filters plugging à As above
- Slow reaction to Causticizing Efficiency à The plant has a dead time from 2 to 4 hours, depending on the plant. This time is the time to get a reaction from the operator
- Overboiling on the slakers à Lime addition over the operational limits
For this case, the main variables should be:
Table 7 – Main Variables in the Slaking/Causticizing for Pulp and Paper
|
Controlled Variable
|
Manipulated Variable
|
|
Slaker Temperature
|
Reburned Lime Addition
|
|
Causticizing Efficiency
|
Fresh Lime Addition
|
|
Temperature Differential through the causticizing process
|
Liquor Addition
|
|
|
Water Addition
|
The main proven benefits for this system are:
- Maximize causticizing efficiency
- Increase liquor and pulp production, decrease liquor bottlenecks
- Maintain good lime mud settling / filterability
- Provide safe operation:
- Thorough, robust controls
- Better operator visibility to process
- Better operator response to process upsets
- Better operator visibility to process
2.7 MPC for Lime Kiln
The main objective for this area is to convert lime mud from causticizing to quick lime for the slaker. The reaction is the following
CaCO3 + Heat à CaO + CO2
The main interactions in this case are:
Table 8 – Main Variables in the Lime Kiln for Pulp and Paper
|
Controlled Variable
|
Manipulated Variable
|
|
Residual O2
|
Id Fan Speed
|
|
Cold End Temperature
|
Energy Flow
|
|
Hot End Temperature
|
Energy Flow
|
The proven main benefits for this application are:
- Production
- Energy Usage dropped by 8%
- Lime Requirement reduced by 4%
- Quality Improvements
- Residual Carbonate Variability reduced by 35%
- Lime Availability Variability reduced by 47%
- Lime Reactivity Variability reduced by 43%
- Kiln Operational Stability
- Cold end Temperature standard deviation reduced by 65%
- Excess Oxygen standard deviation reduced by 60%
- Hot End Temperature standard deviation reduced by 10%
3. CONCLUSIONS
The fact that the MPC requirements are always “study and understand deeply the process, get operators and engineers experience, find the key variables and solve the control problem” is driving other industries to look for this technology. Some examples showed that in the mining industry successful applications of MPC have been successfully implemented in ore grinding, smelting, and in all parts of alumina refining. In the pulp industry, MPC also is now a reality and is has been implemented successfully lime kilns and bleach plants.
But, the main requirement for a good multivariable control implementation in this field is to have a MPC controller and model that is robust to changing plant conditions. An MPC is needed that can handle with large and sudden disturbances, varying transport delays, the anomalies of sensors (e.g.; ore slurry densities and pulp consistencies), non-linear temperature behaviours, and many of the unique issues associated with a given process.
The conclusion is that, even though MPC is used most widely in Petrochemical industries and its implementation and benefits in other industries are proven, MPC could be deployed more frequently and widely in other industries in order to deliver higher productivity and lower costs. Finally, in order to successfully implement multivariable control, is necessary to have a good methodology (Assess à Define à Execute à Deliver à Sustain) and selection of MPC software that is robust and can therefore sustain more time on-control and generate more benefits.